VINYL GLYCOSIDES IN OLIGOSACCHARIDE SYNTHESIS .1. A NEW LATENT-ACTIVEGLYCOSYLATION STRATEGY

Authors
Citation
Gj. Boons et S. Isles, VINYL GLYCOSIDES IN OLIGOSACCHARIDE SYNTHESIS .1. A NEW LATENT-ACTIVEGLYCOSYLATION STRATEGY, Tetrahedron letters, 35(21), 1994, pp. 3593-3596
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
21
Year of publication
1994
Pages
3593 - 3596
Database
ISI
SICI code
0040-4039(1994)35:21<3593:VGIOS.>2.0.ZU;2-J
Abstract
We have developed a never latent-active glycosylation strategy. This g lycosylation strategy is based on isomerisation of substituted allyl g lycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.