OBSERVATION OF SPIN-LOCKED ELECTRON-SPIN ECHO ENVELOPE MODULATION

Electron spin echo envelope modulation (ESEEM) is observed in a coal s ample utilizing a two-pulse sequence originally proposed by Hartmann a nd Hahn to generate a 'spin-locked echo'. It is experimentally shown t hat this spin-locked ESEEM (SLESEEM) is similar to three-pulse ESEEM r ather than conventional two-pulse ESEEM with respect to the presence o r absence of the sum and the difference frequencies, and the echo deca y time. Besides, no phase-cycling is required for the SLESEEM experime nt. A qualitative explanation of the new phenomena is suggested.