Cs. Chern et al., HETEROEPITAXIAL GROWTH OF BA1-XSRXTIO3 YBA2CU3O7-X BY PLASMA-ENHANCEDMETALORGANIC CHEMICAL-VAPOR-DEPOSITION, Applied physics letters, 64(23), 1994, pp. 3181-3183
Epitaxial Ba1-xSrTiO3(BST)/YBa2Cu3O7-x, heterostructures with superior
electrical and dielectric properties have been fabricated by plasma-e
nhanced metalorganic chemical vapor deposition (PE-MOCVD). Data of x-r
ay diffraction and high resolution transmission electron microscopy sh
owed that [100] oriented Ba1-xSrxTiO3 layers were epitaxially deposite
d on epitaxial (001) YBa2Cu3O7-x, layers. The leakage current density
through the Ba1-xSrxTiO3 films was about 10(-7) A/cm2 at 2 V (about 2
X 10(5) V/cm) operation. Moreover, the results of capacitance-temperat
ure measurements showed that the PE-MOCVD Ba1-xSrxTiO3 films had Curie
temperatures of about 30-degrees-C and a peak dielectric constant of
600 at zero bias voltage. The Rutherford backscattering spectrometry a
nd x-ray diffraction results showed that the BST film composition was
controlled between Ba0.75Sr0.25TiO3 and Ba0.8Sr0.2TiO3. The structural
and electrical properties of the Ba1-xSrxTiO3/YBa2CuO7-x heterostruct
ure indicated that conductive oxide materials with close lattice to Ba
1-xSrxTiO3 can be good candidates for the bottom electrode.