SENSITIVITY ANALYSIS OF COMPLEX CHEMICAL-EQUILIBRIA IN HETEROGENEOUS SYSTEMS

Authors
Citation
I. Fishtik et D. Geana, SENSITIVITY ANALYSIS OF COMPLEX CHEMICAL-EQUILIBRIA IN HETEROGENEOUS SYSTEMS, Berichte der Bunsengesellschaft fur Physikalische Chemie, 101(2), 1997, pp. 200-208
Citations number
40
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
ISSN journal
00059021 → ACNP
Volume
101
Issue
2
Year of publication
1997
Pages
200 - 208
Database
ISI
SICI code
0005-9021(1997)101:2<200:SAOCCI>2.0.ZU;2-Y
Abstract
Sensitivity analysis of an equilibrium multiple chemical reaction syst em with several pure condensed phases and one ideal gas phase is consi dered. It is shown that, in this case, response equilibria also play a n important role. The particularity of such systems is that the system 's response may be presented as a sum of contributions coming only fro m those response equilibria defined by gas phase species. The effect o f temperature, pressure and initial amounts of species is analyzed for gasification of coal (graphite).