PEROXIDES AS CONSTITUENTS OF PLANTS .15. IRREGULAR MONOTERPENE PEROXIDES FROM ACHILLEA-FILIPENDULINA LAM

Authors
RUCKER G MANNS D KORBER N BREUER J
Citation
G. Rucker et al., PEROXIDES AS CONSTITUENTS OF PLANTS .15. IRREGULAR MONOTERPENE PEROXIDES FROM ACHILLEA-FILIPENDULINA LAM, Archiv der pharmazie, 327(5), 1994, pp. 277-282
Citations number
10
Categorie Soggetti
Chemistry,"Pharmacology & Pharmacy
Journal title
Archiv der pharmazie → ACNP
ISSN journal
03656233
Volume
327
Issue
5
Year of publication
1994
Pages
277 - 282
Database
ISI
SICI code
0365-6233(1994)327:5<277:PACOP.>2.0.ZU;2-L
Abstract
From Achillea filipendulina LAM. (Asteraceae) two hitherto unknown dia stereomeric, irregular acyclic monoterpene peroxides 5, 6 of santolina triene type have been isolated (4alpha- and 4beta-peroxyachipendole). The constitution of 5 was confirmed by X-ray analysis. Reduction of 5 and 6 results in the formation of the alcohols 8 and 9, respectively. Constitutions of 8 and 9, reported in lit., have to be corrected. In addition, ascaridole (1), trans-pinocarveylhydroperoxide (2) and isoly ratylhydroperoxide A (3) and B (4) have been found.