FOURIER-TRANSFORM INFRARED-SPECTRUM OF CLCN - ANALYSIS OF THE NU(1)-NU(2)+NU(3), AND ASSOCIATED HOT BANDS(NU(3), 2)

Citation
A. Saouli et al., FOURIER-TRANSFORM INFRARED-SPECTRUM OF CLCN - ANALYSIS OF THE NU(1)-NU(2)+NU(3), AND ASSOCIATED HOT BANDS(NU(3), 2), Journal of molecular spectroscopy, 165(2), 1994, pp. 349-357
Citations number
15
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
ISSN journal
00222852
Volume
165
Issue
2
Year of publication
1994
Pages
349 - 357
Database
ISI
SICI code
0022-2852(1994)165:2<349:FIOC-A>2.0.ZU;2-U
Abstract
The Fourier transform spectra of ClCN have been recorded between 2860 to 3030 cm-1 with a resolution of 0.0026 cm-1. The nu1 + nu3 and 2nu2 + nu3 bands and the associated hot bands have been analyzed. A band-by -band analysis has been performed and also, for the first time, a glob al analysis has been made including all available data for the rotatio nal and rovibrational energies of both (ClCN)-Cl-35-C-12-N-14 and (ClC N)-Cl-37-C-12-N-14 isotopomers. The 2nu2 + nu3 band has been analyzed for the less abundant isotopic species (ClCN)-Cl-35-C-13-N-14, (ClCN)- Cl-35-C-12-N-15, and (ClCN)-Cl-37-N-14. (C) 1994 Academic Press, Inc.