NEW MATERIALS FOR SENSORS .1. TRIS(1,10-PHENANTHROLINE)IRON(II) COMPLEXES - INFLUENCE OF 4,7-DONOR SUBSTITUTION ON THE REDOX POTENTIAL

Authors
LEVIS M LUNING U MULLER M SCHMITTEL M WOHRLE C
Citation
M. Levis et al., NEW MATERIALS FOR SENSORS .1. TRIS(1,10-PHENANTHROLINE)IRON(II) COMPLEXES - INFLUENCE OF 4,7-DONOR SUBSTITUTION ON THE REDOX POTENTIAL, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(5), 1994, pp. 675-682
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
5
Year of publication
1994
Pages
675 - 682
Database
ISI
SICI code
0932-0776(1994)49:5<675:NMFS.T>2.0.ZU;2-L
Abstract
Several new 4,7-donor substituted 1,10-phenanthrolines were synthesize d and the corresponding tris(1,10-phenanthroline)iron(II) complexes we re studied by cyclic voltammetry. All iron(II) complexes showed fully reversible waves at scan rates between 50 and 500 mV/s. For some redox systems the kinetics in their reaction with chlorine was studied. Com plexes 7k and 7l significantly extent the potential range of tris(1,10 -phenanthroline)iron(II) complexes.