A PENTAMETHYLCYCLOPENTADIENYL LIGAND FUNCTIONALIZED WITH A PENDANT PYRIDYL GROUP - CRYSTAL-STRUCTURE OF ITS FERROCENE-TYPE IRON COMPLEX

Authors
SIEMELING U NEUMANN B STAMMLER HG
Citation
U. Siemeling et al., A PENTAMETHYLCYCLOPENTADIENYL LIGAND FUNCTIONALIZED WITH A PENDANT PYRIDYL GROUP - CRYSTAL-STRUCTURE OF ITS FERROCENE-TYPE IRON COMPLEX, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(5), 1994, pp. 683-686
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
5
Year of publication
1994
Pages
683 - 686
Database
ISI
SICI code
0932-0776(1994)49:5<683:APLFWA>2.0.ZU;2-7
Abstract
The novel cyclopentadiene HMe(4)C(5)CH(2)CMe(2)py [py = 2-(4-tert-buty l)pyridyl] 2H has been prepared from tetramethylfulvene and lithiated 2-isopropyl-4-tert-butylpyridine. Lithiation of 2H with Bu(n)Li and su bsequent reaction with FeCl2 yields the ferrocene (2)(2)Fe, which crys tallizes in the triclinic space group P (1) over bar with a = 8.368(1) , b = 8.468(1), c = 14.313(1) Angstrom, alpha = 80.64(1), beta = 86.67 (1), gamma = 80.12(1)degrees and V = 985.4(2) Angstrom(3).