COMMENTS ON - HYDRATE DISSOCIATION ENTHALPY AND GUEST SIZE

Authors
SKOVBORG P RASMUSSEN P
Citation
P. Skovborg et P. Rasmussen, COMMENTS ON - HYDRATE DISSOCIATION ENTHALPY AND GUEST SIZE, Fluid phase equilibria, 96, 1994, pp. 223-231
Citations number
8
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
Fluid phase equilibria → ACNP
ISSN journal
03783812
Volume
96
Year of publication
1994
Pages
223 - 231
Database
ISI
SICI code
0378-3812(1994)96:<223:CO-HDE>2.0.ZU;2-P
Abstract
Sloan and Fleyfel (Sloan, E.D. and Fleyfel, F., 1992. Hydrate dissocia tion enthalpy and guest size. Fluid Phase Equilibria, 76: 123-140) cla im that the dissociation enthalpies of hydrates are determined by the size of the guest molecules, and that they are independent of the type and concentration of the guest gas. This conclusion does not seem to be obvious when the effect of the different amounts of water per mole of gas are eliminated from the data.