TEMPERATURE-DEPENDENCE OF THE PARAMETERS CHARACTERIZING THE TRANSFORMATION PROCESSES IN UNDERPOTENTIAL MONOLAYER ADSORBATE OF LEAD ON AG(111) AT LOW AND HIGH COVERAGES

Authors
DIMITROV N POPOV A KASHCHIEV D VITANOV T
Citation
N. Dimitrov et al., TEMPERATURE-DEPENDENCE OF THE PARAMETERS CHARACTERIZING THE TRANSFORMATION PROCESSES IN UNDERPOTENTIAL MONOLAYER ADSORBATE OF LEAD ON AG(111) AT LOW AND HIGH COVERAGES, Electrochimica acta, 39(7), 1994, pp. 957-960
Citations number
24
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
39
Issue
7
Year of publication
1994
Pages
957 - 960
Database
ISI
SICI code
0013-4686(1994)39:7<957:TOTPCT>2.0.ZU;2-5
Abstract
The temperature dependence of the rate constant and the effective diff usion coefficient of incorporation of lead atoms from an underpotentia l monolayer adsorbate on Ag(111) into the silver crystal lattice at lo w and high coverages is investigated. The transfer activation energy i n both cases and the lateral bond energy of the lead atoms in the adso rbate are determined. The resulting energy values compare favourably w ith those known from the literature.