Z. Surowiak et al., PECULIARITIES OF THE SWITCHING PROCESS IN POLYCRYSTALLINE THIN FERROELECTRIC-FILMS OF PZT TYPE, Thin solid films, 245(1-2), 1994, pp. 157-163
One of the basic properties of thin ferroelectric films is the ability
to switch polarization under the influence of an external electric fi
eld. The application of such thin films as memory devices is based on
this phenomenon. The switching process of the thin films has some dist
inctive features. These include, for example, the dependence of the sw
itching time on the electrode surface and an anomalous variation of th
e switching time curve with the amplitude of bipolar rectangular elect
ric voltage impulses. To describe the physical nature of these peculia
rities a simple model is developed. The qualitative compatibility betw
een experiment and the model is shown on the basis of the Pb(Zr,Ti,B',
B'')O3 (PZT)-type thin films with the chemical constitution Pb(Zr0.53T
i0.45W0.01Cd0.01)O3.