SLIDING SPARK SPECTROSCOPY - A NEW EXCITATION SOURCE FOR GENERATING ATOMIC-EMISSION SPECTRA FOR ANALYSIS

Citation
A. Golloch et T. Seidel, SLIDING SPARK SPECTROSCOPY - A NEW EXCITATION SOURCE FOR GENERATING ATOMIC-EMISSION SPECTRA FOR ANALYSIS, Fresenius' journal of analytical chemistry, 349(1-3), 1994, pp. 32-35
Citations number
6
Categorie Soggetti
Chemistry Analytical
ISSN journal
09370633
Volume
349
Issue
1-3
Year of publication
1994
Pages
32 - 35
Database
ISI
SICI code
0937-0633(1994)349:1-3<32:SSS-AN>2.0.ZU;2-Z
Abstract
In this paper a newly developed technique, the so-called ''Sliding Spa rk Spectrometry'' is described. The method, with a comparatively simpl e system, allows direct in-situ analysis of handy, compact non-conduct ive material without prior sample preparation. A new excitation source for optical emission spectroscopy has been developed. The basic princ iple of the method is the thermal vaporization, ionization and excitat ion of a small amount of surface substrate using a train of high-curre nt sliding sparks. The material components in the spark plasma are act ivated to emit radiation. From the atomic spectrum, informations about the composition and the element concentration in the sample can be ob tained. With the use of the sliding spark spectrometer, a rapid analys is, especially of chlorine containing waste plastics and their inorgan ic additives can be carried out.