A. Golloch et T. Seidel, SLIDING SPARK SPECTROSCOPY - A NEW EXCITATION SOURCE FOR GENERATING ATOMIC-EMISSION SPECTRA FOR ANALYSIS, Fresenius' journal of analytical chemistry, 349(1-3), 1994, pp. 32-35
In this paper a newly developed technique, the so-called ''Sliding Spa
rk Spectrometry'' is described. The method, with a comparatively simpl
e system, allows direct in-situ analysis of handy, compact non-conduct
ive material without prior sample preparation. A new excitation source
for optical emission spectroscopy has been developed. The basic princ
iple of the method is the thermal vaporization, ionization and excitat
ion of a small amount of surface substrate using a train of high-curre
nt sliding sparks. The material components in the spark plasma are act
ivated to emit radiation. From the atomic spectrum, informations about
the composition and the element concentration in the sample can be ob
tained. With the use of the sliding spark spectrometer, a rapid analys
is, especially of chlorine containing waste plastics and their inorgan
ic additives can be carried out.