SYNTHESIS AND CRYSTAL-STRUCTURE OF THE COMPLEX (NO3)2(CH3OH)2]CENTER-DOT-BZIMPY-CENTER-DOT-2CH3OH

Authors
WANG JQ ZHU Y WANG SX GAO YC SHI QZ
Citation
Jq. Wang et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF THE COMPLEX (NO3)2(CH3OH)2]CENTER-DOT-BZIMPY-CENTER-DOT-2CH3OH, Polyhedron, 13(9), 1994, pp. 1405-1409
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
9
Year of publication
1994
Pages
1405 - 1409
Database
ISI
SICI code
0277-5387(1994)13:9<1405:SACOTC>2.0.ZU;2-O
Abstract
The reaction of the ligand 2,6-bis(benzimidazol-2-yl) pyridine (bzimpy ) with Lu(NO3)3.6H2O led to the formation of the title complex [Lu(bzi mpy-H) (NO3)2(CH3OH)2].bzimpy.2CH3OH, in which bzimpy-H is the mono an ion derived by deprotonation of bzimpy. The lutetium atom is nine coor dinate, and has one tridentate bzimpy-H anionic ligand, two bidentate NO3 groups, and two CH3OH molecules, bonded in a distorted tricapped t rigonal prismatic geometry.