ENERGETICS OF THE TETRACHLOROPHOSPHONIUM CATION, PCL4(-),G, THE HEXACHLOROPHOSPHATE ANION, PCL6(-),G AND METASTABLE PHOSPHORUS (V) CHLORIDE[PCL4(-)][CL-],C()]2[PCL6()

Authors
JENKINS HDB SHARMAN L FINCH A GATES PN
Citation
Hdb. Jenkins et al., ENERGETICS OF THE TETRACHLOROPHOSPHONIUM CATION, PCL4(-),G, THE HEXACHLOROPHOSPHATE ANION, PCL6(-),G AND METASTABLE PHOSPHORUS (V) CHLORIDE[PCL4(-)][CL-],C()]2[PCL6(), Polyhedron, 13(9), 1994, pp. 1481-1482
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
9
Year of publication
1994
Pages
1481 - 1482
Database
ISI
SICI code
0277-5387(1994)13:9<1481:EOTTCP>2.0.ZU;2-X
Abstract
Lattice potential energy calculations made on [PCl4+]2[PCl6-][Cl-] lea d to an estimate of the lattice energy of this metastable phase of pho sphorus (V) chloride to be 956 kJ mol-1 (corresponding to 319 kJ mol-1 per PCl5 formula unit). The known stability characteristics of alkali metal hexachlorophosphates enable the estimation of the enthalpy of f ormation of PCl6-, g to be in the range: -908 less-than-or-equal-to DE LTA(f)H0(PCl6-, g) less-than-or-equal-to -896 kJ mol-1, similarly, +39 7 kJ mol-1 greater-than-or-equal-to DELTA(f)H0(PCl4+, g) greater-than- or-equal-to + 391 kJ mol-1.