SYNTHESIS AND CRYSTAL-STRUCTURE OF [ME4C2CP2SMCL-CENTER-DOT-THF]2

Authors
SUN CD WEI GC JIN ZS CHEN WQ
Citation
Cd. Sun et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF [ME4C2CP2SMCL-CENTER-DOT-THF]2, Polyhedron, 13(9), 1994, pp. 1483-1487
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
9
Year of publication
1994
Pages
1483 - 1487
Database
ISI
SICI code
0277-5387(1994)13:9<1483:SACO[>2.0.ZU;2-S
Abstract
Me4C2(C5H4MgCl)2(THF) (THF = tetrahydrofuran) reacts with anhydrous Sm Cl3 in THF to give [Me4C2CP2SMCl.THF]2. The molecule is a dimer. Sm1 a nd Sm2 are bridged unsymmetrically by two chlorine atoms [Sm(1)-CI(1) 2.787(2), Sm(1)-Cl(2) 2.848(2), Sm(2)-Cl(1) 2.823(2), Sm(2)-Cl(2) 2.79 5(2) angtrom]. Two centroids of cyclopentadienyl's two chlorine atoms, and an oxygen of THF form a distorted trigonal bipyramid around samar ium. The effective coordination number of samarium is 9.