Nanocomposites of alpha-Fe and alpha-Al2O3, prepared by high-energy ba
ll milling, exhibit coercivities which are enhanced by about two order
s of magnitude with respect to the bulk value. The degree of enhanceme
nt depends on the volume fraction (x(upsilon)) of Fe, with a maximum f
or x(upsilon) almost-equal-to 0.25. The effect is ascribed to the prod
uction of single-domain magnetic grains. Mossbauer spectroscopy reveal
s the presence of iron oxide phases which could not be seen by x-ray a
nd electron diffraction measurements.