Measurements of electron paramagnetic resonance (EPR) at 9 and 35 GHz
between 2 and 300 K in single crystals and powder samples of CuGeO3 ar
e presented. Below 14 K a large decrease in the intensity of the Cu2EPR signal is observed. The data can be interpreted as due to a spin-P
eierls transition. However, an alternative interpretation in terms of
a simple structural transition cannot be ruled out. An opening of an e
nergy gap of approximately 25 K is calculated from the analysis.