STRUCTURE OF CARBONYLCHLORO(ETA-1-CYCLOPENTADIENYL) (METHYLDIPHENYLPHOSPHINE)PLATINUM

Authors
CROSS RJ FARRUGIA LJ KUMA KEA
Citation
Rj. Cross et al., STRUCTURE OF CARBONYLCHLORO(ETA-1-CYCLOPENTADIENYL) (METHYLDIPHENYLPHOSPHINE)PLATINUM, Journal of organometallic chemistry, 471(1-2), 1994, pp. 273-276
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
471
Issue
1-2
Year of publication
1994
Pages
273 - 276
Database
ISI
SICI code
0022-328X(1994)471:1-2<273:SOC(>2.0.ZU;2-Z
Abstract
The molecular structure of the title compound shows the cyclopentadien yl ring to be near planar, eta1-bonded, and trans to the tertiary phos phine. Compounds of this geometry react with Ag+ to produce [Pt(eta5-C 5H5)(CO)(PR3)]+; these in turn regenerate the same isomers of the eta1 -C5H5 complexes on subsequent halide treatment. Reasons for the failur e to observe other geometries for compounds [PtCl(eta1-C5H5)(CO)(PR3)] are discussed.