Mr. Grant et al., THE ROLE OF COPPER SMELTING IN THE PRECOLONIAL EXPLOITATION OF THE ROOIBERG TIN FIELD, South African journal of science, 90(2), 1994, pp. 85-90
Two arsenical copper artefacts, found at Rooiberg in the northern Tran
svaal, have been analysed by instrumental neutron activation analysis
and particle-induced X-ray emission. The results are presented and the
compositions are compared with earlier reports. Dating of charcoal in
clusions in one of the artefacts by accelerator mass spectrometry plac
es its manufacture between the 11th and 13th century AD, in comparison
with the period between the 15th and 17th century AD for a tin artefa
ct from the same area. Possible palaeo-metallurgical smelting techniqu
es are considered in relation to the probable mineralogy of the copper
, arsenic and tin in these ore deposits. The evidence is consistent wi
th indigenous discovery of tin metallurgy from copper or iron producti
on. Rooiberg most likely supplied tin to the Zimbabwe culture area dur
ing the Zimbabwe period and perhaps as early as the K2 and Mapungubwe
periods.