This paper describes the preparation of new alkynes bearing furanic su
bstituents and their polymerization by catalytic systems based on tran
sition metal halides in order to obtain novel materials with original
properties because of the presence of both furan moieties and alternat
e single and double bonds. However, difficulties arising from the spec
ific reactivity of the heterocycle in our experimental conditions led
us to envisage an indirect way to obtain well-defined products, using
an aromatic polymer as the precursor.