DILATOMETRIC STUDY OF THE ISOTROPIC-SMECTIC F-TRANSITION OF 10O.14

Citation
Nvs. Rao et al., DILATOMETRIC STUDY OF THE ISOTROPIC-SMECTIC F-TRANSITION OF 10O.14, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 49(4-5), 1994, pp. 559-562
Citations number
12
Categorie Soggetti
Chemistry Physical",Physics
ISSN journal
09320784
Volume
49
Issue
4-5
Year of publication
1994
Pages
559 - 562
Database
ISI
SICI code
0932-0784(1994)49:4-5<559:DSOTIF>2.0.ZU;2-P
Abstract
The compound N(p-n-decyloxy benzylidene)p-n-tetradecyl aniline, (10O.1 4), a higher homologue of the MBBA series, exhibits smectic F and smec tic G phases. Dilatometric studies inferred strong pre-transitional ef fects in a large temperature range. DSC results confirmed the first or der nature of the IF and FG transitions. The exponential growth of con tinuous six fold hexagonal order across the isotropic-smectic F phase transition is estimated from the density studies with an exponent b = 0.75.