REACTION OF ME2SBR2 AND PRN3PL2 WITH TIN METAL-POWDER - A NOVEL ROUTETO METAL THIOETHER COMPLEXES AND THE 1ST TIN(IV) PHOSPHINE COMPLEX CONTAINING IODIDE LIGANDS

Authors
BRICKLEBANK N GODFREY SM MCAULIFFE CA PRITCHARD RG
Citation
N. Bricklebank et al., REACTION OF ME2SBR2 AND PRN3PL2 WITH TIN METAL-POWDER - A NOVEL ROUTETO METAL THIOETHER COMPLEXES AND THE 1ST TIN(IV) PHOSPHINE COMPLEX CONTAINING IODIDE LIGANDS, Journal of the Chemical Society, Chemical Communications, (6), 1994, pp. 695-696
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1994
Pages
695 - 696
Database
ISI
SICI code
0022-4936(1994):6<695:ROMAPW>2.0.ZU;2-Q
Abstract
Tin metal powder reacts readily with both Me2SBr2 and Prn3PI2 in dieth yl ether under ambient conditions, producing the novel SnBr4(SMe2)2, w hich contains both cis and trans isomers within the unit cell, and the first complex of stoichiometry SnI4(PR3)2 to be isolated: both comple xes have been crystallographically characterised.