INTRAMOLECULAR NUCLEOPHILIC CATALYSIS OF GLUCOSIDE HYDROLYSIS BY THE 2-PHOSPHATE GROUP

Authors
KIRBY AJ STROMBERG R
Citation
Aj. Kirby et R. Stromberg, INTRAMOLECULAR NUCLEOPHILIC CATALYSIS OF GLUCOSIDE HYDROLYSIS BY THE 2-PHOSPHATE GROUP, Journal of the Chemical Society, Chemical Communications, (6), 1994, pp. 709-710
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1994
Pages
709 - 710
Database
ISI
SICI code
0022-4936(1994):6<709:INCOGH>2.0.ZU;2-8
Abstract
4-Nitrophenyl beta-D-glucoside tetraphosphate is hydrolysed 100 times faster than the 2-methoxy derivative, by way of the 1,2-cyclic phospha te diester, which is solvolysed by attack at phosphorus.