SYNTHESIS OF HOMO-BIMETALLIC AND HETEROBIMETALLIC COMPLEXES INCORPORATING THE [(ETA(5)-C5H4)CME2(ETA(5)-C9H6)] LIGAND

Authors
DIAMOND GM GREEN MLH POPHAM NA CHERNEGA AN
Citation
Gm. Diamond et al., SYNTHESIS OF HOMO-BIMETALLIC AND HETEROBIMETALLIC COMPLEXES INCORPORATING THE [(ETA(5)-C5H4)CME2(ETA(5)-C9H6)] LIGAND, Journal of the Chemical Society, Chemical Communications, (6), 1994, pp. 727-728
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1994
Pages
727 - 728
Database
ISI
SICI code
0022-4936(1994):6<727:SOHAHC>2.0.ZU;2-5
Abstract
The new bimetallic complexes )MCl2{(eta5-C5H4)CMe2(eta5-C9H6)}MCl2(et a5-C5H5)] (M = Zr, M = Zr, Hf; M = Hf, M- = Zr, Hf), Cl2{(eta5-C5H4)C Me2(eta5-C9H6)}ZrCl2(eta5-C5Me5)], ta5-C5H5)ZrCl2{(eta5-C5H4)CMe2(eta5 -C9H6)}Rh(CO)2] and ta5-C5H5)ZrCl2{(eta5-C5H4)CMe2(eta5-C9H6)}Mn(CO)3] have been prepared from the precursors [{Me2C(eta5-C5H4)(eta2-C9H6)}M (eta5-C5H5)Cl] (M = Zr 1, Hf 2); the X-ray crystal structure of 1 is r eported.