THE MECHANISM OF ESCHERICHIA-COLI DETHIOBIOTIN SYNTHETASE - THE CLOSURE OF THE UREIDO RING OF DETHIOBIOTIN INVOLVES FORMATION OF A CARBAMIC-PHOSPHATE MIXED ANHYDRIDE

Citation
Rl. Baxter et Hc. Baxter, THE MECHANISM OF ESCHERICHIA-COLI DETHIOBIOTIN SYNTHETASE - THE CLOSURE OF THE UREIDO RING OF DETHIOBIOTIN INVOLVES FORMATION OF A CARBAMIC-PHOSPHATE MIXED ANHYDRIDE, Journal of the Chemical Society, Chemical Communications, (6), 1994, pp. 759-760
Citations number
5
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
6
Year of publication
1994
Pages
759 - 760
Database
ISI
SICI code
0022-4936(1994):6<759:TMOEDS>2.0.ZU;2-A
Abstract
The final intermediate in the enzymatic synthesis of the ureido ring o f D-dethiobiotin 1 from (7R,8S)-7,8-diaminononanoate 2 catalysed by E. coli dethiobiotin synthetase is the phosphoric acid anhydride 4 of th e carbamate 3.