THE MECHANISM OF ESCHERICHIA-COLI DETHIOBIOTIN SYNTHETASE - THE CLOSURE OF THE UREIDO RING OF DETHIOBIOTIN INVOLVES FORMATION OF A CARBAMIC-PHOSPHATE MIXED ANHYDRIDE
Rl. Baxter et Hc. Baxter, THE MECHANISM OF ESCHERICHIA-COLI DETHIOBIOTIN SYNTHETASE - THE CLOSURE OF THE UREIDO RING OF DETHIOBIOTIN INVOLVES FORMATION OF A CARBAMIC-PHOSPHATE MIXED ANHYDRIDE, Journal of the Chemical Society, Chemical Communications, (6), 1994, pp. 759-760
The final intermediate in the enzymatic synthesis of the ureido ring o
f D-dethiobiotin 1 from (7R,8S)-7,8-diaminononanoate 2 catalysed by E.
coli dethiobiotin synthetase is the phosphoric acid anhydride 4 of th
e carbamate 3.