PLANAR CHIRAL ARYLALDEHYDEIMINE TRICARBONYLCHROMIUM COMPLEXES IN THE ASYMMETRIC BAYLIS-HILLMAN COUPLING REACTION

Authors
KUNDIG EP XU LH SCHNELL B
Citation
Ep. Kundig et al., PLANAR CHIRAL ARYLALDEHYDEIMINE TRICARBONYLCHROMIUM COMPLEXES IN THE ASYMMETRIC BAYLIS-HILLMAN COUPLING REACTION, Synlett, (6), 1994, pp. 413-414
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
6
Year of publication
1994
Pages
413 - 414
Database
ISI
SICI code
0936-5214(1994):6<413:PCATCI>2.0.ZU;2-0
Abstract
The DABCO-catalyzed coupling reaction of methyl acrylate and acrylonit rile with enantiomerically pure planar chiral o-substituted (benzaldeh yde tosylimine) Cr(CO)3 complexes after metal removal provides chiral amines in high yields and enantiomeric excess.