PALLADIUM CARBENOIDS FROM ENOLATES OF ALPHA-SULFONYL EPSILON-ACETYLENIC ESTERS, NITRILES OR KETONES - EVIDENCE FOR THE EXISTENCE OF THESE INTERMEDIATES

Authors
MONTEIRO N GORE J VANHEMELRYCK B BALME G
Citation
N. Monteiro et al., PALLADIUM CARBENOIDS FROM ENOLATES OF ALPHA-SULFONYL EPSILON-ACETYLENIC ESTERS, NITRILES OR KETONES - EVIDENCE FOR THE EXISTENCE OF THESE INTERMEDIATES, Synlett, (6), 1994, pp. 447-449
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
6
Year of publication
1994
Pages
447 - 449
Database
ISI
SICI code
0936-5214(1994):6<447:PCFEOA>2.0.ZU;2-2
Abstract
The existence of a vinyl palladium carbenoid is proved by a set of rea ctions previously described for other types of carbenoids : dimerizati on, cyclopropanation, intramolecular capture by a keto group, addition of an alkaline sulfinate.