The 52-color asteroid survey (Bell et al., 1988) together with the 8-c
olor asteroid survey (Zellner et al., 1985) provide a data set of aste
roid spectra spanning 0.3-2.5 mum. An artificial neural network cluste
rs these asteroid spectra based on their similarity to each other. We
have also trained the neural network with a categorization learning ou
tput layer in a supervised mode to associate the established clusters
with taxonomic classes. Results of our classification agree with Thole
n's classification based on the 8-color data alone. When extending the
spectral range using the 52-color survey data, we find that some modi
fication of the Tholen classes is indicated to produce a cleaner, self
-consistent set of taxonomic classes. After supervised training using
our modified classes, the network correctly classifies both the traini
ng examples, and additional spectra into the correct class with an ave
rage of 90% accuracy. Our classification supports the separation of th
e K class from the S class, as suggested by Bell et al. (1987), based
on the near-infrared spectrum. We define two end-member subclasses whi
ch seem to have compositional significance within the S class: the So
class, which is olivine-rich and red, and the Sp class, which is pyrox
ene-rich and less red. The remaining S-class asteroids have intermedia
te compositions of both olivine and pyroxene and moderately red contin
ua. The network clustering suggests some additional structure within t
he E-, M-, and P-class asteroids, even in the absence of albedo inform
ation, which is the only discriminant between these in the Tholen clas
sification. New relationships are seen between the C class and related
G, B, and F classes. However, in both cases, the number of spectra is
too small to interpret or determine the significance of these separat
ions.