The chemical modification of n- and p-type hydrogen-passivated Si(100)
surfaces by a scanning tunneling microscope (STM) is reported. The mo
dified areas have been examined with STM, Auger electron spectroscopy,
scanning electron microscopy, and atomic force microscopy. Comparison
of these characterization techniques indicates the features are both
chemical and topographic in nature and are the result of local oxidati
on of the substrate. In addition, pattern transfer for the defined reg
ions has been demonstrated with both thermal oxidation and HBr reactiv
e-ion etching.