CRYSTAL-STRUCTURE OF THE HEPTAMOLYBDATE (VI) (PARAMOLYBDATE) (NH3)3[PD(NH3)4]3MO7O24

Authors
LALIGANT Y
Citation
Y. Laligant, CRYSTAL-STRUCTURE OF THE HEPTAMOLYBDATE (VI) (PARAMOLYBDATE) (NH3)3[PD(NH3)4]3MO7O24, European journal of solid state and inorganic chemistry, 31(3), 1994, pp. 211-222
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
31
Issue
3
Year of publication
1994
Pages
211 - 222
Database
ISI
SICI code
0992-4361(1994)31:3<211:COTH((>2.0.ZU;2-K
Abstract
(NH3)3[Pd(NH3)4]3Mo7O24 is monoclinic (space group P2(1)/c, Z = 4) wit h a = 10.658(1)angstrom, b = 20.628(2)angstrom, c = 17.551(2)angstrom and beta = 113.038(7)degrees. The structure was refined from single cr ystal data using 4009 independent X-ray reflections to R1 = 0.0364. Th e crystal structure of (NH3)3[Pd(NH3)4]3Mo7O24 is built up by isolated PdN4 square planes and [Mo7O24]6- clusters of seven MoO6 octahedra id entical with those observed in the heptamolybdates of Na+, K+, NH4+ an d [CH6N3]+.