Citation
N. Kuhn et al., IMIDAZOLE DERIVATIVES .9. STABILIZATION O F SELENIUM DIIODIDE BY COMPLEXATION, Chemische Berichte, 127(5), 1994, pp. 849-851
Citations number
29
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00092940
Volume
127
Issue
5
Year of publication
1994
Pages
849 - 851
Database
ISI
SICI code
0009-2940(1994)127:5<849:ID.SOF>2.0.ZU;2-L
Abstract
Stable selenium diiodide complexes 2 are obtained by the reaction of t
he 2-selenoxoimidazolines 1 with iodine. An X-ray structure analysis o
f 2c reveals its monomeric nature. In the trigonal bipyramid, the iodo
substituents are situated in axial positions forming elongated iodine
bonds [Se-I(1) 2.854(1), Se-I(2) 2.768(1) angstrom; I(1)-Se-I(2) 175.
4(0)degrees].