Ri. Cukier et M. Morillo, MODIFICATION OF TUNNELING DYNAMICS BY THE APPLICATION OF RANDOM EXTERNAL FIELDS, Chemical physics, 183(2-3), 1994, pp. 375-384
We investigate the possibility of modifying the tunneling of a particl
e between two states by the application of an external field. The fiel
d couples to the dipole moment of the tunnel object. A phenomenologica
l Hamiltonian is introduced which permits investigation of external fi
elds which have both a random and a time varying systematic component.
A numerical solution of the stochastic equations of motion characteri
zing the population evolution is carried out by averaging over stochas
tic trajectories, for a wide range of parameter values which describe
the tunnel splitting and the systematic and random properties of the e
xternal field. For certain limiting cases, we obtain analytic approxim
ations describing the system dynamics, and compare these solutions wit
h those obtained by the numerical method. We also investigate external
fields that satisfy a precise connection between frequency and amplit
ude, whereby the resulting Floquet quasi-energies are degenerate, and
produce state populations that vary periodically in time. The fluctuat
ion induced modification of the population evolution is assessed for t
hese Floquet fields. We find that it is possible to control tunneling
by the use of external fields, even if they have a random component.