MODIFICATION OF TUNNELING DYNAMICS BY THE APPLICATION OF RANDOM EXTERNAL FIELDS

Citation
Ri. Cukier et M. Morillo, MODIFICATION OF TUNNELING DYNAMICS BY THE APPLICATION OF RANDOM EXTERNAL FIELDS, Chemical physics, 183(2-3), 1994, pp. 375-384
Citations number
37
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
183
Issue
2-3
Year of publication
1994
Pages
375 - 384
Database
ISI
SICI code
0301-0104(1994)183:2-3<375:MOTDBT>2.0.ZU;2-J
Abstract
We investigate the possibility of modifying the tunneling of a particl e between two states by the application of an external field. The fiel d couples to the dipole moment of the tunnel object. A phenomenologica l Hamiltonian is introduced which permits investigation of external fi elds which have both a random and a time varying systematic component. A numerical solution of the stochastic equations of motion characteri zing the population evolution is carried out by averaging over stochas tic trajectories, for a wide range of parameter values which describe the tunnel splitting and the systematic and random properties of the e xternal field. For certain limiting cases, we obtain analytic approxim ations describing the system dynamics, and compare these solutions wit h those obtained by the numerical method. We also investigate external fields that satisfy a precise connection between frequency and amplit ude, whereby the resulting Floquet quasi-energies are degenerate, and produce state populations that vary periodically in time. The fluctuat ion induced modification of the population evolution is assessed for t hese Floquet fields. We find that it is possible to control tunneling by the use of external fields, even if they have a random component.