S. Fiol et al., THE PROTONATION CONSTANTS OF GLYCINE IN NACL AT 25-DEGREES-C BASED ONTHE PITZER AND SCATCHARD MODELS DATA-ANALYSIS BY RIDGE-REGRESSION, Berichte der Bunsengesellschaft fur Physikalische Chemie, 98(2), 1994, pp. 164-171
Citations number
29
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
We have potentiometrically determined the protonation constants of gly
cine in NaCl solutions of variable ionic strength. The data thus obtai
ned have been analysed by using the interaction models of Scatchard an
d Pitzer. The presence of multicollinearity among the explanatory vari
ables of the model has been evidenced through the coefficients of the
correlation matrix and the variance inflation factor (VIF). We have ap
plied the ridge regression (RR) to address the problem arising from mu
lticollinearity and the results are critically compared with those obt
ained by ordinary least squares regression (OLS).