REBa2Cu3Oy superconductors with rare earth (RE) ions with large radii
(RE: La, Nd, Sm) exhibit relatively low T(c) due to the presence of RE
-Ba solid solution. We have found that this solid solution can be supp
ressed if these superconductors are melt processed in a reduced oxygen
atmosphere. We have also found that critical current densities of the
se superconductors are higher than those of melt processed YBa2Cu3Oy w
ith fine Y2BaCuO5 inclusions in a high field region. The irreversibili
ty line was also shifted toward the higher H-T region. We believe that
flux pinning in these superconductors is ascribable to a finely distr
ibuted RE(Ba1-x, REx)2Cu3Oy phase in a good superconductive matrix.