We have examined the correlations between direct surface-finish metrol
ogy techniques and normal-incidence, soft x-ray reflectance measuremen
ts of highly polished x-ray multilayer mirrors. We find that, to maint
ain high reflectance, the rms surface roughness of these mirrors must
be less than approximately 1 angstrom over the range of spatial freque
ncies extending approximately from 1 to 100 mum-1 (i.e., spatial wavel
engths from 1 mum to 10 nm). This range of spatial frequencies is acce
ssible directly only through scanning-probe metrology. Because the sur
face-finish Fourier spectrum of such highly polished mirrors is descri
bed approximately by an inverse power law (unlike a conventional surfa
ce), bandwidth-limited rms roughness values measured with instruments
that are sensitive to only lower spatial frequencies (i.e., optical or
stylus profileres) are generally uncorrelated with the soft x-ray ref
lectance and can lead to erroneous conclusions regarding the expected
performance of substrates for x-ray mirrors.