CLUSTER CHEMISTRY .95. SOME MORE CHEMISTRY OF RU3(MU-DPPM)(CO)10 - REACTIONS WITH ALLYL BROMIDE, DIMETHYL DISULFIDE AND AUCL(PPH3), AND PREPARATION OF SOME COMPLEXES CONTAINING TERTIARY PHOSPHINES AND PHOSPHITES - X-RAY STRUCTURE OF RU3(MU-H)(MU-SME)(MU-DPPM)(CO)8

Authors
BRUCE MI HUMPHREY PA SURYNT RJ TIEKINK ERT
Citation
Mi. Bruce et al., CLUSTER CHEMISTRY .95. SOME MORE CHEMISTRY OF RU3(MU-DPPM)(CO)10 - REACTIONS WITH ALLYL BROMIDE, DIMETHYL DISULFIDE AND AUCL(PPH3), AND PREPARATION OF SOME COMPLEXES CONTAINING TERTIARY PHOSPHINES AND PHOSPHITES - X-RAY STRUCTURE OF RU3(MU-H)(MU-SME)(MU-DPPM)(CO)8, Australian Journal of Chemistry, 47(3), 1994, pp. 477-486
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
47
Issue
3
Year of publication
1994
Pages
477 - 486
Database
ISI
SICI code
0004-9425(1994)47:3<477:CC.SMC>2.0.ZU;2-F
Abstract
Reactions between Ru3(mu-dppm)(CO)io and several reagents have been st udied. With allyl bromide, cluster breakup occurs to give binuclear Ru 2(mu-Br)(mu-C3H5)(mu-dPPM)(CO)4. With Me2S2, binuclear RU2(mu-SMe)2(mu -dppm)(CO)4 and trinuclear RU3(mu-H)(mu-SMe)(mu-dppm)(CO)8 are obtaine d; the X-ray structure of the latter has been determined. With AuCl(PP h3), addition to one Ru-Ru bond gives AuRu3(mu-Cl)(mu-dppm)(CO)8(PPh3) . Some data on tertiary phosphine substituted products formed in react ions with PMe3, PPh3, P(C6H4Me-3)3, P(C6H4Me-4)3, P(OMe)3, P(OCH2CF3)3 , dppe and Fe(eta-CsH4PPh2)2 are also given.