SYNTHESIS AND STRUCTURE OF MONONUCLEAR AND BINUCLEAR COPPER(II) COMPLEXES WITH POLYFUNCTIONAL NITROXIDE IDENE)-2,2,5,5-TETRAMETHYL-3-IMIDAZOLIDINE-1-OXYL, [CU(LH)(2)(H2O)(2)] AND [CU(2)L(2)(H2O)(5)] - CATEPILLAR-LIKE REACTION

Authors
OVCHARENKO VI VOSTRIKOVA KE PODOPLELOV AV ROMANENKO GV IKORSKII VN REZNIKOV V
Citation
Vi. Ovcharenko et al., SYNTHESIS AND STRUCTURE OF MONONUCLEAR AND BINUCLEAR COPPER(II) COMPLEXES WITH POLYFUNCTIONAL NITROXIDE IDENE)-2,2,5,5-TETRAMETHYL-3-IMIDAZOLIDINE-1-OXYL, [CU(LH)(2)(H2O)(2)] AND [CU(2)L(2)(H2O)(5)] - CATEPILLAR-LIKE REACTION, Polyhedron, 16(8), 1997, pp. 1279-1289
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
8
Year of publication
1997
Pages
1279 - 1289
Database
ISI
SICI code
0277-5387(1997)16:8<1279:SASOMA>2.0.ZU;2-Q
Abstract
Cu-II reacted with the polyfunctional nitroxide lidene)-2,2,5,5-tetram ethyl-3-imidazolidine-1-oxyl (H(2)L; Cu/H(2)L = 1:2) to yield Cu(LH)(2 )(H2O)(2), which was characterized by strong fixation of water molecul es exclusively by hydrogen bonds. In the interaction of Cu(LH)(2)(H2O) with an additional amount of Cu-II (Cu/H(2)L = 1:1), the ligands move d towards each other in parallel directions to form the binuclear comp ound Cu(2)L(2)(H2O). This process is very unusual in coordination chem istry. Copyright (C) 1997 Elsevier Science Ltd.