SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF BINUCLEAR THIOAZOMETHINE PALLADACYCLES

Authors
CHATTOPADHYAY P NAYAK MK BHATTACHARYYA SP SINHA C
Citation
P. Chattopadhyay et al., SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF BINUCLEAR THIOAZOMETHINE PALLADACYCLES, Polyhedron, 16(8), 1997, pp. 1291-1295
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
8
Year of publication
1997
Pages
1291 - 1295
Database
ISI
SICI code
0277-5387(1997)16:8<1291:SASCOB>2.0.ZU;2-M
Abstract
Several 1,2-bis(2-thio(N-benzylidene)anilines)ethane [(RC(6)H(4)CH = N C6H4SCH2)(2)] (4) and 1,3-bis(2-thio(N-benzylidene)anilines)propane [( RC(6)H(4)CH = NC6H4SCH2)(2))(2)CH2] (5), R = H (a), 11-CH3 (b), 11-OCH 3 (c), 11-Cl (d) and 11-NO2 (e)] have been synthesized and reacted wit h Pd(OAc)(2) in boiling benzene. The binuclear cyclopalladated acetato complexes (8/9) thus obtained reacted with LiCl, giving the chloro co mplexes having the coordination sphere [Pd(C,N,S)Cl-2](2) (10/11). The mod of ligand binding was established using high-resolution H-1 NMR a nd IR data. Copyright (C) 1997 Elsevier Science Ltd.