2ND AND 3RD ROW TRANSITION-METAL COMPLEXES OF 1,1'-BI-2-NAPHTHOL AND THE X-RAY CRYSTAL-STRUCTURES OF (BU(4)(N)N) [MOO2(ACAC)(BINO)] (1) AND(BU(4)(N)N)2(H2BINO)(2)[MO2O7] (2)
Wp. Griffith et al., 2ND AND 3RD ROW TRANSITION-METAL COMPLEXES OF 1,1'-BI-2-NAPHTHOL AND THE X-RAY CRYSTAL-STRUCTURES OF (BU(4)(N)N) [MOO2(ACAC)(BINO)] (1) AND(BU(4)(N)N)2(H2BINO)(2)[MO2O7] (2), Polyhedron, 16(8), 1997, pp. 1323-1329
The new complexes [MoO2(BINO)(acac)](-) (H2BINO = 1,1'-bi-2-naphthol a
nd acac = acetylacetonate), [Mo2O5(BINO)(2)](2-), [MO(2)(BINO)(2)](2-)
(M = Mo, W, Os) and [M(PPh(3))(2)(BINO)] (M = Pd, Pt) have been prepa
red. The X-ray crystal structures of the title compounds 1 and 2 are d
escribed and the vibrational spectra of the complexes reported. Copyri
ght (C) 1997 Elsevier Science Ltd.