HYDROTRIS(PYRAZOLYL)BORATE MOLYBDENUM CHEMISTRY - SPIN TRIPLET 16-ELECTRON CARBONYL DERIVATIVES OF MOLYBDENUM(II), AND THE X-RAY STRUCTURE OF THE MO(V) OXO COMPOUND (HB(3,5-ME(2)C(3)N(2)H)(3))MOOI2

Authors
SALEH AA PLEUNE B FETTINGER JC POLI R
Citation
Aa. Saleh et al., HYDROTRIS(PYRAZOLYL)BORATE MOLYBDENUM CHEMISTRY - SPIN TRIPLET 16-ELECTRON CARBONYL DERIVATIVES OF MOLYBDENUM(II), AND THE X-RAY STRUCTURE OF THE MO(V) OXO COMPOUND (HB(3,5-ME(2)C(3)N(2)H)(3))MOOI2, Polyhedron, 16(8), 1997, pp. 1391-1397
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
8
Year of publication
1997
Pages
1391 - 1397
Database
ISI
SICI code
0277-5387(1997)16:8<1391:HMC-ST>2.0.ZU;2-U
Abstract
The hydrotris(3, 5-dimethylpyrazolyl) borate complexes TpMo(CO)(2)X ( X = Cl, I) are rare examples of 16-electron carbonyl derivatives with a spin tripler ground state, which exhibit relatively sharp contact-sh ifted H-1 NMR spectra. Oxidation of TpMoI(CO)(2) led to the isolation and crystallographic characterization of TpMoOI2. Copyright 1997 Els evier Science Ltd.