Polycrystalline high quality freestanding 300-mu m-thick diamond films
were doped by diffusion of B and Li under electric bias in order to f
abricate vertical p-n junctions. Circular contacts were obtained by hi
gh dose ion implantation of B and Li. The I-V characteristics were rec
tifying. When illuminated by deuterium lamp, an open circuit voltage w
as 2.6 eV. The shape of the I-V characteristic under illumination poin
ts to the existence of shunt and series resistances. The obtained stru
cture is most probably a p-n junction with bad contacts. (C) 1997 Amer
ican Institute of Physics.