CHARACTERIZATION OF AN UNUSUAL REACTION-PRODUCT OF TIN(II) CHLORIDE WITH SODIUM N,N-DIETHYLDITHIOCARBAMATE

Citation
R. Selvaraju et al., CHARACTERIZATION OF AN UNUSUAL REACTION-PRODUCT OF TIN(II) CHLORIDE WITH SODIUM N,N-DIETHYLDITHIOCARBAMATE, Polyhedron, 13(6-7), 1994, pp. 903-908
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
ISSN journal
02775387
Volume
13
Issue
6-7
Year of publication
1994
Pages
903 - 908
Database
ISI
SICI code
0277-5387(1994)13:6-7<903:COAURO>2.0.ZU;2-T
Abstract
The reaction of sodium N,N-diethyldithiocarbamate trihydrate with tin( II) chloride under aerobic conditions yields the unexpected cis-dichlo robis(N,N-diethyldithiocarbamato)tin(IV) which has been characterized by X-ray crystallography. This illustrates the tin to be in a distorte d octahedral configuration; the coordination valencies being provided by the two chlorines in cis positions and two dithiocarbamates in cis- orientations. The Sn-119 NMR of the complex is consistent with the pre sence of six coordinated tin(IV). The formation of the complex is expl ained via the intermediate product, tetraethylthiuram disulphide.