G. Krishnan et Cp. Prabhakaran, MASS-SPECTRAL STUDIES ON SOME DITHIOCARBAMATO COMPLEXES OF MANGANESE(III), IRON(III), COBALT(III) AND CADMIUM(II), Polyhedron, 13(6-7), 1994, pp. 983-986
Mass spectra of 10 complexes of manganese(III), iron(III), cobalt(III)
and cadmium(II) with dithiocarbamates derived from diethylamine, pipe
ridine and morpholine have been investigated. The complexes of mangane
se(III), iron(III) and cobalt(III) show similar fragmentation behaviou
r, while cadmium(II) behaves differently. Molecular ion peaks are obse
rved only for cadmium(II) and cobalt(III) complexes. The base peak in
all cases is [ML2]+ (M = Mn, Fe, Co or Cd and L = dithiocarbamato grou
p).