SPECTROSCOPY AND STRUCTURE OF COMPLEXES WITH LN-N BONDS .3. STRUCTUREAND SPECTROSCOPY OF ETHYLENEDIAMMONIUM OCTAAZI DODINEODYMATE

Authors
STARYNOWICZ P BUKIETYNSKA K RYBAROMANOWSKI W DOMINIAKDZIK G GOLAB S
Citation
P. Starynowicz et al., SPECTROSCOPY AND STRUCTURE OF COMPLEXES WITH LN-N BONDS .3. STRUCTUREAND SPECTROSCOPY OF ETHYLENEDIAMMONIUM OCTAAZI DODINEODYMATE, Polyhedron, 13(6-7), 1994, pp. 1069-1075
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
6-7
Year of publication
1994
Pages
1069 - 1075
Database
ISI
SICI code
0277-5387(1994)13:6-7<1069:SASOCW>2.0.ZU;2-A
Abstract
The crystal structure and electronic (absorption and emission) spectra of a new neodymium azide complex are presented. The structure is comp osed of ethylenediammonium cations and anionic polymeric network built up from azide anions and neodymium cations. The neodymium environment consists of nine nitrogen atoms. The absorption spectra show high int ensity of the hypersensitive I-4(9/2) double line arrow pointing right 4G5/2, 2G7/2 transition. The Judd-Ofelt analysis is presented.