SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE 1ST COORDINATIVELY SATURATED ALKYL CARBONYL COMPLEX OF THE PLATINUM-GROUP

Authors
DEFELICE V FERRARA ML GIORDANO F RUFFO F
Citation
V. Defelice et al., SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE 1ST COORDINATIVELY SATURATED ALKYL CARBONYL COMPLEX OF THE PLATINUM-GROUP, Gazzetta chimica italiana, 124(2), 1994, pp. 117-119
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
124
Issue
2
Year of publication
1994
Pages
117 - 119
Database
ISI
SICI code
0016-5603(1994)124:2<117:SAXCOT>2.0.ZU;2-H
Abstract
A coordinatively saturated methyl platinum(II) complex (1) including c arbon monoxide in the coordination sphere is described. X-Ray analysis discloses an undistorted trigonal bipyramidal (TBP) geometry with the carbonyl group in equatorial position. An insertion reaction yielding a carbonyl/acetyl derivative is observed upon treatment of the produc t with CO under fairly mild conditions.