ALUMINUM CONTENT DEPENDENCE OF MILKY TRANSPARENT CONDUCTING ZNO-AL FILMS WITH TEXTURED SURFACE PREPARED BY DC MAGNETRON SPUTTERING

Transparent and conductive milky zinc oxide (ZnO) films with a texture d surface were prepared by d.c. magnetron sputtering using ZnO targets with an Al2O3 content in the range 0-2.0 wt.%. The grain growth and s urface morphology were considerably dependent on the Al2O3 content, ra nging from a disk-like textured surface for undoped ZnO films to a wed ge-like textured surface for Al-doped (ZnO:Al) films prepared with a c ontent above 0.5 wt.%. The resistivity of milky films post-annealed in an H-2 atmosphere was independent of Al2O3 content from 0.75 to 2.0 w t.%, whereas it was reduced by a factor of 100 with Al impurity doping . The transmittance in the near-IR range of milky ZnO:Al films prepare d with an Al2O3 content of 0.75 wt.% was considerably better than that of films prepared with a content of 2.0 wt.%. For solar cell applicat ions of these films it was found that the optimal Al2O3 content of the ZnO target is about 0.75 wt.%. A sheet resistance as low as 2 OMEGAsq uare-1, a transmittance of 78% ana a haze ratio of 65% at a wavelength of 550 nm were obtained for milky ZnO:Al films 3 mum thick prepared w ith an Al2O3 content of 0.75 wt.%.