Schottky diodes of Si-TiSi2 type have been prepared by annealing of sp
uttered Ti films on p-Si in a rapid thermal processing system. The the
rmal treatments were carried out in a nitrogen atmosphere at different
temperatures and times. The aim of this work is the study of the stag
es of the silicide growth as well as the thermal stability of the diod
es. Rutherford backscattering spectra were measured to analyse the inf
luence of the thermal treatments on the elemental depth distribution i
n the diode structures. The ideality factor and the diode barrier heig
ht were determined from electrical measurements. The diodes show an id
eality factor very close to unity. The barrier height phi(B) was calcu
lated from both I-V and C-V curves, resulting in fairly close values.
The values of phi(B) decrease from 0.55 eV for the as-deposited sample
s to a stable value of 0.51 eV for the diodes treated in the 635-1090-
degrees-C temperature range for 20 s. Even after annealing at the high
est temperatures, the diodes show an excellent rectifying behaviour.