R. Velotta et al., KINETIC-ENERGY DISTRIBUTIONS OF CHARGED FRAGMENTS FROM CO2 DISSOCIATIVE IONIZATION, Journal of physics. B, Atomic molecular and optical physics, 27(10), 1994, pp. 2051-2061
The electron impact ionization of CO2 molecules has been studied in or
der to determine the dissociative paths leading to charged fragments.
The electron impact energy (EIE) ranged in the interval 40-130 eV. Tim
e-of-flight spectroscopy was used to obtain the kinetic-energy distrib
ution (KED) extending down to thermal kinetic-energy fragments. We hav
e evaluated the contribution of indirect processes leading to charged
fragments through CO2 autoionization. The threshold for C2+ production
from CO2 has been measured and a possible production channel is analy
sed.