Ma. Wait et al., EFFECTS OF DUAL SPECTRAL SOURCES ON THE CURING OF POLYIMIDE FILMS BY RAPID ISOTHERMAL PROCESSING, Applied physics letters, 64(24), 1994, pp. 3234-3236
There are fundamental differences between conventional furnace process
ing (CFP) and rapid isothermal processing (RIP). The radiation spectru
m of a conventional furnace consists of photons in the infrared and lo
nger wavelength regions, whereas the spectrum of the incoherent light
sources used in RIP consists of some UV, visible, and infrared photons
. As compared to CFP, the photophysical and photochemical effects asso
ciated with RIP provide the capability of lower temperature processing
. However, a further reduction in processing temperature can be achiev
ed by the use of vacuum ultraviolet (VUV) and UV light sources in conj
unction with a single spectral source RIP. We provide experimental res
ults for the dual spectral source curing of polyimide dielectric films
. Our findings indicate that simultaneous exposure of polyimide sample
s to both VUV and conventional RIP sources during processing cured the
polyimide more rapidly and at lower temperatures than did single spec
tral source RIP alone. These results may be of great importance for th
e RIP of the future generation of semiconductor devices.