K. Gergova et al., ADSORPTION PROPERTIES AND MICROSTRUCTURE OF ACTIVATED CARBONS PRODUCED FROM AGRICULTURAL BY-PRODUCTS BY STEAM PYROLYSIS, Carbon, 32(4), 1994, pp. 693-702
A series of activated carbons has been prepared by steam pyrolysis of
apricot and cherry stones, almond shells, and grape seeds at relativel
y low temperatures of 600, 650, and 700-degrees-C for 1-3 h at each te
mperature. The adsorption properties of the resulting activated carbon
s were studied as a function of the treatment temperature, soak time,
and nature of the precursor. Activated carbons produced from various a
gricultural by-products showed different pore size distributions, depe
nding on pyrolysis/activation conditions. Among the activation conditi
ons used in this study, the treatment at 700-degrees-C for 2 h produce
d the highest N2 BET surface area and pore volume obtained from each p
recursor. The activated carbons were characterized by N2 adsorption, i
odine, and methylene blue adsorption from solution. The microstructure
s of the carbons were examined by optical and scanning electron micros
copy. The adsorption characteristics of the activated carbons produced
from various agricultural by-products were found to be different and
strongly dependent on the composition and structure of the raw materia
ls.